Which esters smell

This seemingly small change results in a striking difference. An ester is formed when an alcohol and carboxylic acids are combined, eliminating a molecule of water in the process. Here's a generic reaction:. An esterification reaction: An alcohol reacts with a carboxylic acid forming an ester new bond is indicated by red hatch line and water.

This reaction is called the Fischer esterification and it's years old. Original image: Libre Texts. So, the chemical definition of an ester is a molecule formed by the combination of an alcohol and a carboxylic acid:. What's especially intriguing about esters is that even when there are only small differences in the number of carbon atoms in either the carboxylic acid part of the ester or the alcohol part the difference in the esters can be significant.

Here are two examples:. Acetic acid is held constant the "acid part" of the molecule and it is combined with six different alcohols to make six different esters. Esters of acetic acid. Note the differences in the ester when it is combined with six different alcohols. Ethyl alcohol, held constant as the alcohol component, is combined with five different carboxylic acids. Esters of ethyl alcohol combined with five different carboxylic acids. Note that the carboxylic acids are nasty smelling, but their ethyl esters are anything but.

Why do esters smell so nice? There could be a number of reasons. There is a genetic advantage for plants to have their fruit eaten; it spreads the seeds allowing new plants to grow. Likewise, animals, birds, and insects may have co-evolved to learn that sweet smells and tastes mean that good and safe — esters are not toxic at the levels found in foods food is available.

Another reason may be that low molecular weight alcohols and carboxylic acids are readily biosynthesized by plants. Or some combination of all of these. Stupid chemistry time! Image: TeeSpy. WHAT is going on??? Always wash with cool water all produce of any kind. Make sure you have not had of of these on-hand. Make sure you have not had of of these on-hand or on your hands. Is it feasible therefore that a pineapple scented ester might be used in paint recipes? Just curious. Thankyou to all reading this question and to anyone who might think they can help.

Thanks James! I wanted to purchase some esters like grape, banana, Apple, etc to enhance my vape oil. Do you have any recommendations? Thank you. Would love a perfume with same scent???

Very Nice, I would like to know if it is possible to use Esters in Pit Toilets, if so how should the procedure be? In my experience, they actually last longer! We make quite a few esters such as methyl oleate, sorbitan esters and 2 ethyl hexyl esters. Hello Sir! I am really impressed with the grafical layout of these chemicals. What I am particularly interested in is the presence of these chemicals in Whisky. I have been making a blog about how the fruity notes etc get into whisky and linking them to chemicals.

This overview is fantastic for that kind of information. I have been trying to make just such an overview, but since I am an engineer and not a chemist, I may have gotten to the limits of my ways. Any Tips in how I can make tables of this kind of information? I am particularly looking at the evaporation temperature and the way in which these chemicals are made during fermentation of spirits.

Can esters that are synthesized from the reaction of acid halides and alcohols produce pleasant smells? I think different proportion of the acid and alcohol makes a big difference in terms of smell.

Do you have a recipe or procedure that you can share? You are commenting using your WordPress. Viewed 41k times.

Improve this question. Jan Rohinb97 Rohinb97 3 3 gold badges 8 8 silver badges 20 20 bronze badges. Smell came first as a simple way of characterising chemicals. When structures of the chemicals started to be understood the term became associated with a particular subset of compounds like benzene and used to describe their electronic configurations.

There are a lot more compounds with interesting smells than compounds with aromaticity in their electronic configuration. I've asked for its "aromatic" character there. It's not to be confused with aromaticity, of course.

It has nothing to do with electronic aromaticity as you seemed to assume in the question. Like I said in the previous comment I meant "aromatic" in the smelly way. Add a comment. Active Oldest Votes. Improve this answer. Dissenter Dissenter I always thought that compounds were classified because they smell.

But it's actually because they were smelly that's why they were classified This is not because molecules are volatile than they smell! I found your answer great but it is more an answer about why can we smell some molecules and not some others. And as I said this is not because molecules are volatiles than they smell. In my town they add a smell in the gas to be able to smell it if there is a problem.

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